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Economic Geology; August 1964; v. 59; no. 5; p. 747-752
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Experimental determination of the reaction chalcopyrite+sulfur=pyrite+bornite from 350 to 500 degrees C

Paul B. Barton, and Priestley Toulmin

The univariant equilibrium curve determined by the electrum-tarnish method, is expressed as a function of temperature and fugacity of sulfur, and extended upward, with gentle curvature, to the invariant point with liquid sulfur at 568 degrees C. The data provide a basis for recognizing disequilibrium in certain assemblages.

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