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U. S. Geological Survey, MS-973, Box 25046, Federal Center, Denver, Colorado 80225
Corresponding author: email, pemsbo{at}usgs.gov
The final event in a complicated hydrothermal history at the Meikle gold
deposit was gold deficient but caused extensive postore dissolution of
carbonate, collapse brecciation, and precipitation of calcite and barite
crystals in the resulting cavities. Although previously interpreted to be part
of the Carlin-type hydrothermal system, crosscutting relationships and U-Th-Pb
geochronology constrain this hydrothermal event to late Pliocene time (ca. 2
Ma), nearly 36 Ma after ore formation. Mineralogic, fluid inclusion, and stable
isotope data indicate that postore hydrothermal fluids were reduced, H2S-rich,
unevolved meteoric waters (
18O
= 17
) of low temperature (ca. 65°C). The
18O
values of barite and calcite indicate that these minerals were in isotopic
equilibrium, requiring that barite SO4 was derived from the oxidation
of reduced sulfur; however, preexisting sulfides in breccia cavities were not
oxidized. The
34S
(15
) values of barite are higher than those of local bulk sulfide and
supergene alunite indicating that SO4 was not derived from supergene
oxidation of local sulfide minerals. The 15 per mil
34S
value suggests that the H2S in the fluids may have been leached from
sulfur-rich organic matter in the local carbonaceous sedimentary rocks. A
reduced H2S-rich fluid is also supported by the bright
cathodoluminescence of calcite which indicates that it is Mn rich and Fe poor.
Calcite has a narrow range of
13C
values (0.31.8
) that are indistinguishable from those of the host
Bootstrap limestone, indicating that CO2 in the fluid was from
dissolution of the local limestone. These data suggest that dissolution and
brecciation of the Bootstrap limestone occurred where H2S-rich fluids
encountered more oxidizing fluids and formed sulfuric acid (H2SO4).
Intense fracturing in the mine area by previous structural and hydrothermal
events probably provided conduits for the descent of oxidized surface water
which mixed with the underlying H2S-rich waters to form the
dissolving acid. The surface-derived fluid apparently contained sufficient
oxygen to produce H2SO4 from H2S but not enough
to alter pyrite to Fe oxide. Although H2S is an important
gold-transporting ligand, the temperature was too low to transport a significant
amount of gold.
The presence of analogous calcite- and barite-lined cavities in other Carlin-type deposits suggests that the generation (and oxidation) of H2S-rich meteoric waters was a common phenomenon in north-central Nevada. Previous sulfur isotope studies have also shown that the Paleozoic sedimentary rocks were the principal source of H2S in Devonian sedimentary exhalative-type, Jurassic intrusion-related, Eocene Carlin-type, and Miocene low-sulfidation gold deposits in the region. The similar sulfur source in all of these systems suggests that basin brines, magmatic fluids, and meteoric waters all evolved to be H2S-rich ore fluids by circulation through Paleozoic sedimentary rocks. Thus, although not directly related to gold mineralization, the recent hydrologic history of the deposit provides important clues to earlier ore-forming processes that were responsible for gold mineralization.
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